... towards excellence in science

An Autonomous Institution, Under the Ministry of Education, Government of India

Swadhin Mandal

Dept: Chemical Sciences (DCS)
E-mail: swadhin.mandal [at]

All Publications:

  1. Ahmed, J.; Prasannan, S.; Vijaykumar, G.; Jose, A.; Raj, M. and Mandal, S. K.. 2017."A new face of phenalenyl-based radicals in the transition metal-free C–H arylation of heteroarenes at room temperature: trapping the radical initiator via C–C ?-bond formation." Chem. Sci., ,
  2. Mukherjee, A.; Sau, S. C. and Mandal, S. K,. 2017."Exploring Closed-Shell Cationic Phenalenyl: From Catalysis to Spin Electronics." Acc. Chem. Res., 50, 1679-1691
  3. 2017."Direct C-H Arylation of Heteroarenes with Aryl Chlorides using Abnormal NHC Coordinated Palladium Catalyst, J. Ahmed, S. C. Sau, S. Prasannan, P. K. Hota, P. K. Vardhanapu, G. Vijaykumar and S. K. Mandal." Eur. J. Org. Chem., 5, 1004-1011
  4. 2017."Development of an antibody-drug conjugate platform using platinum as a linker, N. Gupta, J. Kancharla, S. Kaushik, A. Ansari, S. Hossain, R. Goyal, M. Pandey, J. Sivaccumar, S. Hussain, A. Sarkar, A. Sengupta, S. K. Mandal, M Roy, S. Sengupta." Chem. Sci., 8, 2387-2395
  5. Sau, Samaresh Chandra; Bhattacharjee, R.; Vardhanapu, Pavan Kumar; Vijaykumar, Gonela; Datta, A. and Mandal, Swadhin Kumar. 2016."Metal Free Reduction of CO2 to Methoxyborane Under Ambient Conditions through Borondiformate Formation." Angew. Chem. Int. Ed., 55, 15147
  6. Bhunia, Mrinal; Sahoo, Sumeet Ranjan; Vijaykumar, Gonela; Adhikari, Debasish and Mandal, Swadhin Kumar. 2016."Iron Catalysed Regioselective Dimerization of Terminal Aryl Alkynes." Organometallics, 35, 3775-3780
  7. Bhunia, Mrinal; Hota, Pradip Kumar; Vijaykumar, Gonela; Adhikari, Debasish and Mandal, Swadhin Kumar. 2016."A Highly Efficient Catalyst for Selective Reduction of Imines to Amines: An Abnormal-NHC?Fe(0) Complex in Reduction Chemistry." Organometallics, 35, 2930-2937
  8. Thakur, Arunabha; Vardhanapu, Pavan K; Vijaykumar, Gonela; Hota, Pradip Kr and Mandal, Swadhin K. 2016."Abnormal N-Heterocyclic Carbene Mediated Capture of CO2, N2O and Activation of Small Molecules Under Ambient Condition." Eur. J. Inorg. Chem. , 2016, 913–920
  9. Paira, Rupankar; Singh, Bhagat; Hota, Pradip K; Ahmed, Jasimuddin; Sau, Samaresh Ch; Jhonpeter, Justin and Mandal, Swadhin K. 2016."Phenalenyl Based Radical in Transition Metal Free Catalytic C-H Functionalization." J. Org. Chem., 81, 2432–2441
  10. Vijaykumar, Gonela and Mandal, Swadhin K. 2016."An Abnormal N-heterocyclic Carbene Nickel Catalyst for Reduction of Nitroarenes." Dalton Trans., 45, 7421-7426
  11. Mukherjee, Arup; Sen, Tamal K; Baskaran, S; Sivasankar, C and Mandal, Swadhin K. 2015."Hydrolysis of An Organozirconium Complex: The First Polyoxometallic Heptanuclear Zirconium Oxide." J. Organomet. Chem, 775, 76-79
  12. Paryar, Anand; Vijaykumar, Gonela; Dey, Suman Kr.; Singh, Santosh K; Kurongot, Shreekumar and Mandal, Swadhin K. 2015."Switching Closed-Shell to Open-Shell Phenalenyl: Toward Designing Electroactive Materials." J. Am. Chem. Soc., 137, 5955-5960
  13. Hota, Pradip K; Vijaykumar, Gonela; Paryar, Anand; Sau, Samaresh Ch; Sen, Tamal K and Mandal, Swadhin K. 2015."An Abnormal NHC Based Palladium Dimer: Aqueous Oxidative Heck Coupling Under Ambient Temperature ." Adv. Synth. Catalysis , 357, 3162-3170
  14. Sau, Samaresh Ch; Roy, Sudipta Raha and Mandal, Swadhin K. 2014."Integrating Organometallic Catalysis with Organocatalysis: A Consecutive Catalytic Approach in One-Pot." Chemistry Asian Journal, 9, 2806-2813
  15. Mukherjee, Arup; Samuel, Prinson P; Schulzke, Carola and Mandal, Swadhin K. 2014."Main Group Chemistry of 9-Hydroxophenalenone: Syntheses and Structural Characterization of the Alkaline Earth and Zinc Complexes." J. Chem. Sci. , 126, 1581-1588
  16. Roy, Sudipta Raha; Sau, Samaresh Ch. and Mandal, Swadhin K. 2014."Chemoselective Reduction of the Carbonyl Functionality through Hydrosilylation: Integrating Click Reaction with Hydrosilylation in One Pot ." J. Org. Chem., 79, 9150-9160.
  17. Roy, Sudipta Raha; Nijamuddin, A; Paryar, Anand; Vardhanapu, Pavan; Ghosh, Anup; Mandal, Prasun K; Datta, Ayan and Mandal, Swadhin K. 2014."Phenalenyl in Different Role: Catalytic Activation through the Nonbonding Molecular Orbita." ACS Catalysis , 4, 4307–4319
  18. Santra, Subhankar; Hota, Pradip K; Bhattacharyya, Rangeet; Bera, Parthasarathi; Ghosh, Prasenjit and Mandal, Swadhin K. 2013."Palladium Nanoparticles on Graphite Oxide: Highly Recyclable Catalyst for the Synthesis Biaryl Cores." ACS Catalysis, 3 , 2776?2789
  19. Mukherjee, Arup; Sen, Tamal K; Ghorai, Pradip K and Mandal, Swadhin K. 2013."Organozinc Catalyst on Phenalenyl Scaffold for Intramolecular Hydroamination of Aminoalkenes." Organometallics, 32, 7213–7224
  20. Sen, T K; Sau, S C; Mukherjee, A; Hota, P; Mandal, S K; Maity, D and Koley, D. 2013."Abnormal N-heterocyclic Carbene Main Group Organometallic Chemistry: A Debut to the Homogenous Catalysis." Dalton Trans., 42, 14253 -260
  21. Sau, S C; Roy, S R; Sen, T K; Mullangi, D and Mandal, S K. 2013."An Abnormal N-Heterocyclic Copper(I) Complex in Versatile Click Chemistry." Adv. Synth. Cat., 355, 2982-2991
  22. Mukherjee, A; Sen, T K; Ghorai, P K and Mandal, S K. 2013."The Non-innocent Phenalenyl Unit: An Electronic Nest to Modulate the Catalytic Activity in Hydroamination Reaction." Scientific Reports, 3, 2821
  23. Santra, S; Hota, P K; Bhattacharyya, R; Bera, P; Ghosh, P and Mandal, S K. 2013."Palladium Nanoparticles on Graphite Oxide: Highly Recyclable Catalyst for the Synthesis Biaryl Cores." ACS Catalysis, 3, 2776-2789
  24. Mukherjee, A; Sen, T K; Ghorai, P K and Mandal, S K. 2013."Organozinc Catalyst on Phenalenyl Scaffold for Intramolecular Hydroamination of Aminoalkenes." Organometallics, 32, 7213-7224
  25. Patra, A; Sen, T K; Musie, G T; Mandal, S K and Bera, M. 2013." “A novel copper(II) coordination polymer with carboxylate and isoindol backbones of a bifunctional ligand" 2013, 1047, 317-323. ." J. Mol. Struc., 1047, 317-323
  26. Chakraborty, T; Sen, T K; Singh, H; Das, D; Mandal, S K and Mitra, C. 2013.""Experimental Realization of Thermal Entanglement in a Molecular chain" ." J. Appl. Phys. , 114, 144904
  27. Raman, Karthik V; Kamerbeek, Alexander M.; Mukherjee, Arup; Atodiresei, Nicolae; Sen, Tamal K; Lazic, Predrag; Caciuc, Vasile; Michel, Reent; Stalke, Dietmar; Mandal, Swadhin K; Bluegel, Stephan; Muenzenberg, Markus and Moodera, Jagadeesh. 2013."Interface-engineered templates for molecular spin memory devices." Nature, 493, 509-513
  28. Sen, Tamal K; Mukherjee, Arup; Modak, Arghya; Mandal, Swadhin K and Koley, Debasis. 2013."Substitution Effect on Phenalenyl Backbone in the Rate of Organozinc Catalyzed ROP of Cyclic Esters." Dalton Trans., 42, 1893-1904
  29. Patra, Ayan; Sen, Tamal K.; Ghorai, Atanu; Musie, Ghezai T.; Mandal, Swadhin K.; Ghosh, Utpal and Bera, Manindranath. 2013."Synthesis, Structure, Spectroscopic Characterization and Protein Binding Affinity of New Water Soluble Hetero- and Homometallic Tetranuclear [CuII2ZnII2] and [CuII4] Clusters." Inorganic Chemistry, 52, 2880?2890
  30. Mukherjee, Arup; Sen, Tamal K; Mandal, Swadhin K; Maity, Bholanath and Koley, Debasis. 2013."Construction of Oxygen-bridged Multimetallic Assembly: Dual Catalysts for Hydroamination Reactions." RSC Advances, 3, 1255–1264
  31. Dey, Suman K; Honecker, Andreas; Mitra, Partha; Mandal, Swadhin K. and Mukherjee, Arindam. 2012."Magneto-structural studies of tetranuclear manganese [MnIII2MnII2] complexes of 9-hydroxy phenalenone with weak ?-? interactions." Eur. J. Inorg. Chem, XX, 5814-5824
  32. Chakraborty, Tanmoy; Sen, Tamal K; Singh, Harkirat; Das, Diptaranjan; Mandal, Swadhin K. and Mitra, Chiranjib. 2012."Comparative study of magnetic behaviour in three classic molecular magnets." Solid State Commun, 152, 1945-1950
  33. Mukherjee, Arup; Sen, Tamal K.; Ghorai, Pradip Kr.; Samuel, Prinson P.; Schulzke, Carola and Mandal, Swadhin K. 2012."Phenalenyl-Based Organozinc Catalysts for Intramolecular Hydroamination Reactions: A Combined Catalytic, Kinetic, and Mechanistic Investigation of the Catalytic Cycle." Chemistry -A European Journal, 18, 10530-545
  34. Santra, Subhankar; Ranjan, Priyadarshi; Bera, Parthasarathi; Ghosh, Prasenjit and Mandal, Swadhin K.. 2012."Anchored palladium nanoparticles onto single walled carbon nanotubes: Recyclable heterogeneous nanocatalyst in the synthesis of N-containing heterocycles via copper free acyl Sonogashira reaction." RSC Advances, 2, 7523–7533
  35. Sen, Tamal K; Mukherjee, Arup; Modak, Arghya; Ghorai, Pradip Kr.; Kratzert, Daniel; Granitzka, Markus; Stalke, Dietmar and Mandal, Swadhin K.. 2012."Phenalenyl Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design Catalyst." Chemistry A European Journal, 18, 54-58
  36. Sau, Samaresh Chandra; Santra, Subhankar; Sen, Tamal K; Mandal, Swadhin K and Koley, Debasis. 2012."Abnormal N-Heterocyclic Carbene Palladium Complex: Living Catalyst for Activation of Aryl Chlorides in Suzuki–Miyaura Cross Coupling." Chemical Communications, 48, 555-557
  37. Patra, Ayan; Sen, Tamal K; Bhattacharyya, Rangeet; Mandal, Swadhin K and Bera, Manindranath. 2012."Diversity of carboxylate binding in an unusual tetranuclear zinc cluster: Correlation between spectroscopic investigations ." RSC Advances, 2, 1774-1777
  38. Mandal, Swadhin K and Roesky, Herbert W. 2012."Group 14 Hydrides with Low-Valent Elements for Small Molecules Activation." Accounts of Chemical Research, 45, 298-307