PUBLICATIONS

Peer-Reviewed Publications:

34. Li, M.; Li, H.; De, P.; Sumerlin, B. S. Thermoresponsive Block Copolymer-Protein Conjugates Prepared by Grafting-From via RAFT Polymerization. Macromol. Rapid Commun. 2010, In press.

33. Li, M.; De, P.; Li, H.; Sumerlin, B. S. Conjugation of RAFT-generated polymers to proteins by two consecutive thiol-ene reactions. Polymer Chemistry, 2010, 1, 854-859.

32. De, P.; Gondi, S. R.; Roy, D.; Sumerlin, B. S. Boronic Acid-Terminated Polymers: Synthesis by RAFT and Subsequent Supramolecular and Dynamic Covalent Self-Assembly. Macromolecules, 2009, 42(15), 5614-5621.

31. De, P.; Li, M.; Gondi, S. R.; Sumerlin, B. S. Temperature-Regulated Activity of Responsive Polymer-Protein Conjugates Prepared by Grafting-from via RAFT Polymerization. Journal of the American Chemical Society. 2008, 130(34), 11288-11289.

30. Li, M.; De, P.; Gondi, S. R.; Sumerlin, B. S. End group transformations of RAFT-generated polymers with bismaleimides: functional telechelics and modular block copolymers. J. Polym. Sci. Part A: Polym. Chem. 2008, 46(15), 5093-5100. This article was recognized as one of the hottest polymer science article in 2008 from Wiley and Wiley-VCH journals.

29. Li, M.; De, P.; Gondi, S. R.; Sumerlin, B. S. Responsive polymer-protein bioconjugates prepared by RAFT polymerization and Copper-catalyzed azide-alkyne click chemistry. Macromol. Rapid Commun. 2008, 29(12-13), 1172-1176. Highlighted in the June 2008 edition of Materials View.

28. De, P.; Gondi, S. R.; Sumerlin, B. S. Folate-conjugated thermoresponsive block copolymers: highly efficient conjugation and solution self-assembly. Biomacromolecules, 2008, 9(3), 1064-1070.

27. De, P.; Faust, R. Carbocationic polymerization of isobutylene using methylaluminum bromide coinitiators: synthesis of bromoallyl functional polyisobutylene. Macromolecules, 2006, 39(22), 7527-7533.

26. De, P.; Faust, R. Relative reactivity of C4 olefins toward the polyisobutylene cation. Macromolecules, 2006, 39(20), 6861-6870.

25. De, P.; Faust, R. Synthesis of halogen-free polyisobutylene by in situ hydride transfer to living polyisobutylene from tributylsilane. Polymer Bulletin, 2006, 56(1), 27-35.

24. De, P.; Faust, R. Determination of the absolute rate constants of propagation for ion pairs and free ions in the living cationic polymerization of isobutylene. Macromolecules, 2005, 38(26), 9897-9900.

23. De, P.; Faust, R. Determination of the absolute rate constant of propagation for ion pairs in the cationic polymerization of p-methylstyrene. Macromolecules, 2005, 38(13), 5498-5505.

22. De, P.; Sipos, L.; Faust, R.; Moreau, M.; Charleux, B.; Vairon, J –P. Effect of temperature and determination of the propagation rate constant in the carbocationic polymerization of 2,4,6-trimethylstyrene. Macromolecules, 2005, 38(1), 41-46.

21. De, P.; Faust, R. Determination of the absolute rate constants of propagation for ion pairs in the carbocationic polymerization of p-chlorostyrene. Macromolecules 2004, 37(24), 9290-9294.

20. De, P.; Faust, R. Living carbocationic polymerization of p-methoxystyrene by the p-methoxystyrene hydrochloride/SnBr₄ initiating system: determination of the absolute rate constant of propagation. Macromolecules 2004, 37(21), 7930-7937.

19. De, P.; Faust, R; Schimmel, H.; Ofial, A. R.; Mayr, H. Determination of rate constants in the carbocationic polymerization of styrene: effect of temperature, solvent polarity and Lewis acid. Macromolecules 2004, 37(12), 4422-4433.

18. Balaban, A. T.; Ghiviriga, I.; Czerwinski, E. W.; De, P.; Faust, R. Simple synthesis of a weak nucleophilic base (4-ethyl-2,6-diisopropyl-3,5-dimethylpyridine) evidencing a double Janus Group effect. J. Org. Chem. 2004, 69(2), 536-542.

17. Sivalingam, G.; De, P.; Karthik, R.; Giridhar, M. Thermal degradation kinetics of vinyl polyperoxide copolymers. Polym. Degrad. Stab. 2004, 84(1), 173-179.

16. Sipos, L.; De, P.; Faust, R. Effect of temperature, solvent polarity, and nature of Lewis acid on the rate constants in the carbocationic polymerization of isobutylene. Macromolecules 2003, 36, 8282-8290.

15. De, P.; Sathyanarayana, D. N.; Sadasivamurthy, P.; Sridhar, S. Synthesis, spectral characterization and thermochemical studies on poly(phenyl methacrylate peroxide). J. Appl. Polym. Sci., 2003, 88(9), 2364-2368.

14. De, P.; Sathyanarayana, D. N. Synthesis and characterization of copolyperoxides of indene with styrene, a-methylstyrene and a-phenylstyrene. J. Polym. Sci. Part B: Polym. Phys., 2002, 40(18), 2004-2017.

13. De, P.; Sathyanarayana, D. N. High-pressure kinetics of oxidative copolymerization of styrene with a-methylstyrene. Macromol. Chem. Phys., 2002, 203(15), 2218-2224.

12. De, P.; Sathyanarayana, D. N. Free-radical oxidative copolymerization of indene with vinyl acetate and isopropenyl acetate: synthesis and characterization. J. Appl. Polym. Sci., 2002, 86(3), 639-646.

11. De, P.; Chattopadhyay, S.; Giridhar, M.; Sathyanarayana, D. N. Thermal degradation kinetics of para-substituted poly(styrene peroxide)s in solution. J. Appl. Polym. Sci. 2002, 86(4), 957-961.

10. De, P.; Chattopadhyay, S.; Giridhar, M.; Sathyanarayana, D. N. Kinetics of thermal degradation of vinyl polyperoxides in solution. Polym. Degrad. Stab. 2002, 76(1), 161-170.

9. De, P.; Chattopadhyay, S.; Giridhar, M.; Sathyanarayana, D. N. Thermal degradation studies of para-substituted poly(styrene peroxide)s. Polym. Degrad. Stab. 2002, 76(3), 511-514.

8. De, P.; Sathyanarayana, D. N.; Sadasivamurthy, P.; Sridhar, S. Reactivity ratios for the oxidative copolymerizations of indene with methyl methacrylate and methacrylonitrile. Eur. Polym. J., 2002, 38(5), 847-855.

7. De, P.; Sathyanarayana, D. N. Reactivity ratios for the terpolymerization of methyl methacrylate, vinyl acetate and molecular oxygen. J. Polym. Sci. Part A: Polym. Chem., 2002, 40(4), 564-572.

6. De, P.; Sathyanarayana, D. N. Determination of the reactivity ratios for the oxidative copolymerizations of indene with methyl, ethyl and butyl acrylates. Macromol. Chem. Phys., 2002, 203(3), 573-579.

5. De, P.; Sathyanarayana, D. N. Oxidative copolymerization of indene with p-tert-butylstyrene: synthesis, characterization, thermal analysis and reactivity ratios. J. Polym. Sci. Part A: Polym. Chem., 2002, 40(1), 9-18.

4. De, P.; Sathyanarayana, D. N. Para-substituted poly(styrene peroxide)s: synthesis, characterization, thermal reactivities and chain dynamics studies in solution. Macromol. Chem. Phys., 2002, 203(2), 420-426.

3. De, P.; Sathyanarayana, D. N. Synthesis of poly(1,3-diisopropenylbenzene peroxide). Indian J. Chem., 2001, 40A(9), 1009-1011.

2. De, P.; Sathyanarayana, D. N. Polymerization of vinyl acetate with styrene and a-methylstyrene under high oxygen pressure. Indian J. Chem., 2001, 40A(12), 1282-1287.

1. De, P.; Sathyanarayana, D. N.; Sadasivamurthy, P.; Sridhar, S. Synthesis, structural characterization, thermal studies and chain dynamics of poly(methacrylonitrile peroxide) by NMR spectroscopy. Polymer, 2001, 42(21), 8587-8593.

Other Publications:

20. Sumerlin, B. S.; Li, M.; Li, H.; De, P. Immobilization of RAFT-generated polymers to proteins. Polymeric Materials Science and Engineering 2010, xxx, xxx-yyy.

19. Li, M.; Li, H.; Bapat, A. P.; De, P.; Sumerlin, B. S. Functional polymers and polymer-protein conjugates prepared by RAFT and thiol-ene reactions . Polymer Preprints 2010, 51(2), 689-690.

18. De, P.; Li, M.; Li, H.; Sumerlin, B. S. Responsive polymer-protein conjugates by grafting-from via RAFT polymerization. Polymeric Materials Science and Engineering 2009, 101, 1475-1476.

17. De, P.; Li, M.; Roy, D.; Sumerlin, B. S. Self-assembly of stimuli-responsive polymer-protein conjugates prepared by RAFT polymerization. Polymeric Materials Science and Engineering 2009, 100, 669-670.

16. Sumerlin, B. S.; De, P.; Li, M.; Gondi, S. R. Polymer-protein bioconjugates via grafting-from and grafting-to with RAFT-generated polymers. Polymer Preprints 2008, 49(2), 234-235.

15. Sumerlin, B. S.; De, P.; Gondi, S. R. Responsive block copolymer micelles functionalized with biologically-relevant ligands. Polymer Preprints 2008, 49(2), 1085-1086.

14. De, P.; Gondi, S. R.; Sumerlin, B. S. Folate conjugated responsive polymeric micelles: Synthesis by RAFT polymerization and click chemistry. Polymer Preprints 2008, 49(1), 175-176.

13. De, P.; Li, M.; Gondi, S. R.; Sumerlin, B. S. Polymer-protein bioconjugates via grafting-from by RAFT polymerization and azide-alkyne click chemistry. Polymer Preprints 2008, 49(1), 197-198.

12. De, P.; Li, M.; Gondi, S. R.; Sumerlin, B. S. Responsive polymer-protein bioconjugates by grafting-from via RAFT with the R-group approach. Polymer Preprints 2008, 49(1), 1057-1058.

11. Li, M.; De, P.; Gondi, S. R.; Sumerlin, B. S. Versatile end group modification strategy for RAFT-generated polymers. Polymer Preprints 2008, 49(1), 238-239.

10. Li, M.; De, P.; Gondi, S. R.; Sumerlin, B. S. Responsive polymer-protein bioconjugates prepared by RAFT polymerization and grafting-to via click chemistry. Polymer Preprints 2008, 49(1), 200-201.

9. De, P. Comparative study of the chain dynamics of polymers containing peroxy linkages in the backbone. Polymer Preprints 2005, 46(2), 852-853.

8. De, P.; Faust, R. Capping reactions in cationic polymerization; Kinetic and synthetic utility. Polymer Preprints 2005, 46(2), 847-848.

7. De, P.; Faust, R. Living cationic polymerization of p-methylstyrene using SnCl₄ in dichloromethane and determination of absolute rate constant of propagation. Polymer Preprints 2005, 46(2), 935-936.

6. De, P.; Faust, R. Living carbocationic polymerization of p-methoxystyrene using p-methoxystyrene hydrochloride/SnBr₄ initiating system. Polymer Preprints 2004, 45(2), 736-737.

5. De, P.; Faust, R. Determination of the propagation rate constant in the cationic polymerization of p-chlorostyrene. Polymer Preprints 2004, 45(2), 734-735.

4. De, P.; Faust, R. Cationic polymerization kinetics of styrene and styrene derivatives. Manuscript published in MACRO 2004 - 40th IUPAC World Polymer Congress.

3. De, P.; Munavalli, M. V.; Faust, R. On line visible spectroscopic study on the capping reaction of styrene cations with ditolylethylene. Polymer Preprints 2003, 44(2), 920-921.

2. De, P.; Faust, R.; Schimmel, H.; Mayr, H.; Moreau, M.; Charleux, B.; Vairon, J –P.Determination of the propagation rate constant in the carbocationic polymerization of 2,4,6-trimethylstyrene. Polymer Preprints 2003, 44(2), 804-805.

1. De, P.; Munavalli, M. V.; Faust, R. Determination of the propagation rate constant in the carbocationic polymerization of styrene. Polymer Preprints 2003, 44(1), 1071-1072.

Patents:

1. Faust, R.; De, P. Capping reactions in cationic polymerization; kinetic and synthetic utility. US Patent. WO 2006110647, 2006.

2. Johnson, P.; Stayton, P. S.; Hoffman, A. S.; Convertine, A. J.; Overell, R.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Micelles for intracellular delivery of therapeutic agents. US Patent. WO/2009/140432, 2009.

3. Johnson, P.; Stayton, P. S.; Hoffman, A. S.; Convertine, A. J.; Duvall, C. L.; Benoit, D.; Overell, R.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Micellic assemblies comprising a plurality of copolymers. US Patent. WO/2009/140429, 2009.

4. Johnson, P.; Stayton, P. S.; Hoffman, A. S.; Convertine, A. J.; Duvall, C. L.; Benoit, D.; Lee, C. C.; Overell, R.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Targeted polymer bioconjugates and therapeutic uses thereof. US Patent. WO/2009/140423, 2009.

5. Stayton, P. S.; Hoffman, A. S.; Convertine, A. J.; Duvall, C. L.; Benoit, D.; Overell, R.; Johnson, P.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Polymeric carrier for the delivery of polynucleotides into a living cell. US Patent. WO/2009/140421, 2009.

6. Johnson, P.; Stayton, P. S.; Hoffman, A. S.; Overell, R.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Heterogeneous polymeric micelles and conjugates for intracellular delivery. US Patent. WO/2010/021770, 2010.

7. Prieve, M. G.; Johnson, P. H.; Stayton, P. S.; Hoffman, A. S.; Overell, R. W.; Gall, A. S.; Paschal, A. E. E.; Diab, C.; De. P.; Declue, M. S.; Monahan, S. D. Multiblock copolymers associated with polynucleotides for pharmaceutical compositions. US Patent. WO 2010054266, 2010.

8. Johnson, P.; Stayton, P. S.; Hoffman, A. S.; Overell, R.; Gall, A.; Prieve, M.; Paschal, A.; Diab, C.; De. P. Micelles of hydrophilically shielded membrane-destabilizing copolymers. US Patent. WO 2010053597, 2010.

Book Chapters:

1. De, P.; Faust, R. Carbocationic Polymerization In Macromolecular Engineering; Matyjaszewski, K.; Gnanou, Y.; Leibler, L. Eds.; Wiley-VCH, Weinheim, Germany, Vol. 1, Pages 57-101, 2007.

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