Details of CH3202 (Spring 2025)
Level: 3 | Type: Theory | Credits: 4.0 |
Course Code | Course Name | Instructor(s) |
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CH3202 | Organic Chemistry V | Dibyendu Das, Sureshkumar Devarajulu |
Syllabus |
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Stereochemistry of Acyclic Compounds (5 Lectures)
Stereocentres, Stereoaxis in details Topicity of ligands and faces: Pro-R, Pro-S and Re/Si descriptors. Stereochemistry of Cyclic Compounds (10 Lectures) Conformational analysis: monocyclic compounds, fused and bridged ring compounds Dynamic stereochemistry: conformation and reactivity Elimination (E2), rearrangement, nucleophilic substitution (SN1, SN2, NGP) Stereoelectronic Effects (5 Lectures) Acetals, Esters, Amides and related functions. Reactions at sp3, sp2, and sp carbons. Introduction to asymmetric synthesis (20 Lectures) Basic principles and examples of stereospecific, stereoselective, enantioselective and diastereoselective reactions Cram model, Felkin-Ahn model, Houk model, Cieplak model, EFOE model, and pFacial selectivity |
References |
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References
1. Stereochemistry of Organic Compounds: Principles and Applications by D. Nasipuri. 2. Stereochemistry of Carbon Compounds by E. L. Eliel and S. H. Wilen. 3. Advanced Organic Chemistry: Reaction Mechanism by R. Bruckner. 4. Organic Chemistry by J. Clayden, N. Greeves and S. Warren. |
Course Credit Options
Sl. No. | Programme | Semester No | Course Choice |
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1 | IP | 2 | Not Allowed |
2 | IP | 4 | Not Allowed |
3 | IP | 6 | Not Allowed |
4 | MP | 2 | Not Allowed |
5 | MP | 4 | Not Allowed |
6 | MR | 2 | Not Allowed |
7 | MR | 4 | Not Allowed |
8 | MS | 10 | Elective |
9 | MS | 4 | Not Allowed |
10 | MS | 6 | Core |
11 | MS | 8 | Elective |
12 | RS | 1 | Elective |
13 | RS | 2 | Elective |